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|Original Airdate:||October 20, 2014|
|Next Episode:||"Spirit of the Goat"|
"Viper" is the fifth episode of the first season of Gotham.
Bruce plans to find a way to speak to the board members of Wayne Enterprises to learn their connections to the Arkham District Project. A new drug called "Viper" is hitting the street where the user gains super-strength, but eventually kills them. Maroni plans to rob a casino owned by Falcone, and Cobblepot reveals his past. Gordon learns that "Viper" (which is a prototype of Venom) is being distributed at a charity event held by WellZyn and Wayne Enterprises. Gordon shoots the canister on the roof and former WellZyn employee Stan Potolsky gets exposed, jumping off as he suggests they check out Warehouse 39, where later Gordon and Bullock find nothing. As Mooney makes plans to conspire against Falcone with lover Nikolai, a disguised Liza visits him in the park where she shares her opera music with him.
- Ben McKenzie as James Gordon
- Donal Logue as Harvey Bullock
- David Mazouz as Bruce Wayne
- Sean Pertwee as Alfred Pennyworth
- Robin Lord Taylor as Oswald Cobblepot/Penguin
- Zabryna Guevara as Sarah Essen
- Jada Pinkett Smith as Fish Mooney
- Cory Michael Smith as Edward Nygma
- Camren Bicondova as Selina Kyle
- John Doman as Carmine Falcone
- David Zayas as Sal Maroni
- Makenzie Leigh as Liza
- Danny Mastrogiorgio as Frankie Carbone
- Daniel London as Stan Potolsky
- Kett Turton as Benny
- Genevieve Hudson-Price as Charmagne
- Peter Maloney as Isaac Steiner
- Sharon Washington as Molly Mathis
- Jeremy Davidson as Nikolai
- Margaret Colin as Taylor Reece
- Krista Braun as News Reporter
- Carmine Famiglietti as Cashier